Study on the Application of the (S)-2-tert-Butyl-2-methyl-1,3-benzodioxole-4-carboxylic acid-based On-line HPLC-Exciton CD Analysis to Acyclic 1,3-Diols | Zendy

S. SATO | Zendy; Kumi Shimizu | Zendy; JeongHwan Kim | Zendy; Ei’ichi Ami | Zendy; Kazuaki Akasaka | Zendy; Hiroshi Ohrui | Zendy

Open Access

Study on the Application of the (S)-2-tert-Butyl-2-methyl-1,3-benzodioxole-4-carboxylic acid-based On-line HPLC-Exciton CD Analysis to Acyclic 1,3-Diols

Author(s) -

S. SATO,

Kumi Shimizu,

JeongHwan Kim,

Ei’ichi Ami,

Kazuaki Akasaka,

Hiroshi Ohrui

Publication year - 1998

Publication title -

bioscience biotechnology and biochemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.509

H-Index - 116

eISSN - 1347-6947

pISSN - 0916-8451

DOI - 10.1271/bbb.62.1822

Subject(s) - absolute configuration , enantiomer , vicinal , high performance liquid chromatography , chemistry , carboxylic acid , exciton , stereochemistry , chromatography , organic chemistry , physics , quantum mechanics

The application of the on-line HPLC-exciton CD analysis with (S)-TBMB-carboxylic acid that simultaneously determined the enantiomeric composition and absolute configuration of vicinal diols, diamines and amino alcohols to 1,3-diols was studied. All optical isomers of di-O-(S)-TBMB-carbonyl-1,3-butanediols and 2,4-pentanediols were separated and their absolute configurations were determined without reference samples on line by HPLC.

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