Characterization of Dimers of Hydroquinone Glucosides Produced by Peroxidase-Catalyzed Polymerization | Zendy

Taro Kiso | Zendy; Motohiro Shizuma | Zendy; Seiji Watase | Zendy; Takaaki Kiryu | Zendy; Hiromi Murakami | Zendy; Hirofumi Nakano | Zendy

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Characterization of Dimers of Hydroquinone Glucosides Produced by Peroxidase-Catalyzed Polymerization

Author(s) -

Taro Kiso,

Motohiro Shizuma,

Seiji Watase,

Takaaki Kiryu,

Hiromi Murakami,

Hirofumi Nakano

Publication year - 2007

Publication title -

bioscience biotechnology and biochemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.509

H-Index - 116

eISSN - 1347-6947

pISSN - 0916-8451

DOI - 10.1271/bbb.60660

Subject(s) - hydroquinone , horseradish peroxidase , polymerization , peroxidase , chemistry , reactivity (psychology) , catalysis , polymer chemistry , glucoside , photochemistry , organic chemistry , enzyme , polymer , medicine , alternative medicine , pathology

4'-Hydroxyphenyl alpha-glucoside and 4'-hydroxyphenyl beta-glucoside were polymerized with horseradish peroxidase. The isolated dimers were found to have linkages at C3' of the hydroxyphenyl moieties and proved to be fluorescent. Low accumulation of oligomers was attributed to increasing electrochemical reactivity with polymerization degrees, which were expected from the levels of highest occupied molecular orbital.

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