Synthesis of Atromentin and ItsO-Alkylated Natural Products | Zendy

Yue Qi Ye | Zendy; Hiroyuki Koshino | Zendy; Naoki Abe | Zendy; Takemichi Nakamura | Zendy; Daisuke Hashizume | Zendy; Shunya Takahashi | Zendy

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Synthesis of Atromentin and ItsO-Alkylated Natural Products

Author(s) -

Yue Qi Ye,

Hiroyuki Koshino,

Naoki Abe,

Takemichi Nakamura,

Daisuke Hashizume,

Shunya Takahashi

Publication year - 2010

Publication title -

bioscience biotechnology and biochemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.509

H-Index - 116

eISSN - 1347-6947

pISSN - 0916-8451

DOI - 10.1271/bbb.100451

Subject(s) - ceric ammonium nitrate , alkylation , chemistry , ammonium , crystal structure , ammonium nitrate , organic chemistry , combinatorial chemistry , catalysis , polymer , grafting

The structure of a long-known natural pigment, atromentin, was established by a total synthesis based on double Suzuki-Miyaura coupling and by a single-crystal X-ray analysis of the synthetic sample thereby obtained. A similar strategy including ceric ammonium nitrate (CAN) oxidation was applied to prepare 2-O-methoxyatromentin and thelephantin I.

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