Open AccessAdsorption of Heavy Metal Ions on Virgin and Chemically-Modified Lignocellulosic Materials
Author(s) -
Rima Saliba,
Hélène Gauthier,
Robert Gauthier
Publication year - 2005
Publication title -
adsorption science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.682
H-Index - 36
eISSN - 2048-4038
pISSN - 0263-6174
DOI - 10.1260/0263617054770039
Subject(s) - chemistry , adsorption , metal ions in aqueous solution , aqueous solution , sawdust , metal , cellulose , ion , nuclear chemistry , inorganic chemistry , organic chemistry
Amidoximated wood sawdust (Am-WS) and wood flour (Am-WF) were prepared using the same procedure as described recently for amidoximated cellulose (Am-Cell). The modified supports thus obtained were characterized by IR, TGA and DSC methods. In comparison to the untreated material, such treatment led to a considerable increase in adsorption capacity towards heavy metal ions from aqueous solution. The quantity adsorbed increased with pH, initial metal ion concentration and immersion time. The formation of a 1:1 complex between the amidoxime group and Cu(II), Cr(III) and Cd(II) ions and a 2:1 complex with the Ni(II) ion was demonstrated by the adsorption limit values. Overall, Am-WS and Am-WF exhibited similar behaviour to Am-Cell and are suitable for the treatment of wastewaters containing heavy metal ions.