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Rheology of Silica Sols/Gels Obtained by a Y-Shaped Reactor with a Dilute Method
Author(s) -
Aya Kaide,
Takashi Saeki
Publication year - 2014
Publication title -
journal of chemical engineering of japan
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.206
H-Index - 49
eISSN - 1881-1299
pISSN - 0021-9592
DOI - 10.1252/jcej.13we111
Subject(s) - rheology , viscoelasticity , sodium silicate , viscosity , chemical engineering , materials science , precipitated silica , sulfuric acid , dilution , silicate , hydrophobic silica , creep , composite material , thermodynamics , natural rubber , physics , engineering , metallurgy
Silica sols can be continuously produced by the neutralization of sodium silicate with sulfuric acid using a Y-shaped reactor. The vi scosity of the produced silica sols gradually increases, and gels are finally formed th rough the sol–gel transition. The gelation properties are significantly affected by t he preparation conditions. Here we examined the effect of the dilution of silica sols by water in terms of the gelation properties of the silica sols and gels, using both dynamic viscoelasticity measurement and the creep test. Information that is needed to c ontrol the gelation properties of silica sols and gels for making silica materials into a pr oduct is also presented.

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