Synthesis of Chiral Bis-MOP-type Diphosphines. Chelating Effect in Nickel-catalyzed Phosphination
Author(s) -
Artur R. Abreu,
Andreia F. Peixoto,
Ana R. Almeida,
Mirtha A. O. Lourenço,
A. Neves,
J. Carles Bayón,
Mariette M. Pereira
Publication year - 2012
Publication title -
chemistry letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.492
H-Index - 114
eISSN - 1348-0715
pISSN - 0366-7022
DOI - 10.1246/cl.2013.37
Subject(s) - diphosphines , chemistry , nickel , catalysis , aryl , yield (engineering) , stoichiometry , alkyl , chelation , medicinal chemistry , metal , polymer chemistry , organic chemistry , metallurgy , materials science
Chiral bis-MOP-type diphosphines with alkyl and pyridyl bridges connecting the two binaphthyl units have been synthesized via [NiCl2(dppe)]-assisted phosphination of the corresponding aryl triflate...
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