Open AccessCrystal Structure of a 1:1:1 Molecular Complex of (R)-(+)-2,2′-Dihydroxy-1,1′-binaphthyl,N,N,N′,N′-Tetra(2-butyl)terephthalamide, and Methanol
Author(s) -
Fumio Toda,
Yasunori Tagami,
Quan Hao,
HongTao Fan,
Thomas C. W. Mak
Publication year - 1986
Publication title -
chemistry letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.492
H-Index - 114
eISSN - 1348-0715
pISSN - 0366-7022
DOI - 10.1246/cl.1986.1913
Subject(s) - chemistry , tetra , crystal structure , crystal (programming language) , crystallography , stereochemistry , medicinal chemistry , computer science , programming language
X-Ray analysis of the title complex has shown that the three molecular components are linked by hydrogen bonds to form helical chains parallel to the a axis. The (R)-(+)-2,2′-dihydroxy-1,1′-binaphthyl molecule adopts a transoid conformation with a torsion angle of −95(1)° about the C–C bond joining the aromatic rings