The Chemistry of Disilyne with a Genuine Si–Si Triple Bond: Synthesis, Structure, and Reactivity | Zendy

Akira Sekiguchi | Zendy; Masaaki Ichinohe | Zendy; Rei Kinjo | Zendy

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The Chemistry of Disilyne with a Genuine Si–Si Triple Bond: Synthesis, Structure, and Reactivity

Author(s) -

Akira Sekiguchi,

Masaaki Ichinohe,

Rei Kinjo

Publication year - 2006

Publication title -

bulletin of the chemical society of japan

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.145

H-Index - 99

eISSN - 1348-0634

pISSN - 0009-2673

DOI - 10.1246/bcsj.79.825

Subject(s) - chemistry , triple bond , reactivity (psychology) , stereochemistry , organic chemistry , double bond , medicine , alternative medicine , pathology

In this account, our recent results on the chemistry of a stable silicon-silicon triply-bonded compound, disilyne, including recent advances in the chemistry of stable alkyne analogues of heavier group 14 elements, are described. Our original extremely bulky trialkylsilyl substituent, Dis 2 i PrSi [Dis = CH(SiMe 3 ) 2 ], has enabled the isolation of disilyne as a stable compound, which has been completely characterized by various spectroscopic techniques, as well as X-ray crystallography. Some reactivity of our isolable disilyne will be discussed.

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