Transition Metal-Catalyzed C–C Bond Formation Reactions Using Alkyl Halides | Zendy

Jun Terao | Zendy; Nobuaki Kambe | Zendy

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Transition Metal-Catalyzed C–C Bond Formation Reactions Using Alkyl Halides

Author(s) -

Jun Terao,

Nobuaki Kambe

Publication year - 2006

Publication title -

bulletin of the chemical society of japan

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.145

H-Index - 99

eISSN - 1348-0634

pISSN - 0009-2673

DOI - 10.1246/bcsj.79.663

Subject(s) - chemistry , halide , alkyl , catalysis , reagent , transition metal , organic chemistry , carbon–carbon bond , combinatorial chemistry

This account reviews transition metal-catalyzed C-C bond formation reactions using alkyl halides, which have rarely been used as carbon sources in conventional transition metal-catalyzed systems. In the reactions, ate complexes formed by the reaction of transition metals with a Grignard reagent play important roles as the active catalytic species. The reactions mentioned here are mechanistically new and provide a promising methodology for the construction of carbon frameworks employing alkyl halides.

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