Syntheses of Biliverdin Derivatives Sterically Locked at the CD-Ring Components
Author(s) -
Mostafa A. S. Hammam,
Hiroshi Nakamura,
Yukari Hirata,
Htoi Khawn,
Yasue Murata,
Hideki Kinoshita,
Katsuhiko Inomata
Publication year - 2006
Publication title -
bulletin of the chemical society of japan
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.145
H-Index - 99
eISSN - 1348-0634
pISSN - 0009-2673
DOI - 10.1246/bcsj.79.1561
Subject(s) - chemistry , biliverdin , steric effects , ring (chemistry) , stereochemistry , chromophore , phytochrome , lactone , heme , organic chemistry , heme oxygenase , enzyme , red light , botany , biology
Total syntheses of biliverdin derivatives with a Z-syn, Z-anti, or E-syn CD-ring components were accomplished via new and efficient methods for the construction of sterically locked CD-ring components towards the elucidation of the stereochemistry of the chromophore in phytochromes
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