Open AccessBranched-chain Sugars. VI. Reaction of Methylene Dimagnesium Bromide with Uloses
Author(s) -
Juji Yoshimura,
Kenichi Sato,
Hiroo Wakai,
Masuo Funabashi
Publication year - 1976
Publication title -
bulletin of the chemical society of japan
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.145
H-Index - 99
eISSN - 1348-0634
pISSN - 0009-2673
DOI - 10.1246/bcsj.49.1169
Subject(s) - chemistry , methylene , vicinal , reagent , bromide , wittig reaction , organic chemistry , medicinal chemistry
Application of methylene dimagnesium bromide, instead of the Wittig reagent, to several uloses gave the corresponding methylene derivatives in nearly equal yields, when the hydroxyl groups vicinal to the carbonyl function are protected with alkaline-stable groups.
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