The Chemiluminescence of Luminol and Acetyl-luminol
Author(s) -
Yoshimori Omote,
Takeo Miyake,
Seiya Ohmori,
Noboru Sugiyama
Publication year - 1967
Publication title -
bulletin of the chemical society of japan
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.145
H-Index - 99
eISSN - 1348-0634
pISSN - 0009-2673
DOI - 10.1246/bcsj.40.899
Subject(s) - luminol , chemistry , chemiluminescence , chromatography , photochemistry
Several acetyl derivatives of luminol were synthesized and their chemiluminescence were studied in water or in DMF-water. The role of the amino group in the chemiluminescence was revealed by comparing the chemiluminescence of luminol (I) with that of N-acetyl-luminol (II). Also, it was found that, in the case of the chemiluminescence of I or II in water, the emitting species did not seem to be the corresponding substituted phthalate ion, while in the case of the chemiluminescence in DMF-water, the 3-aminophthalate or 3-acetylaminophthalate ion could be presumed to be the emitting species.
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