English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The classical repertoire of synthetic organic chemistry is short of methods that allow triple bonds to be transformed into (E)-alkenes with high selectivity in the presence of other reducible sites. Recent advances, most notably in ruthenium-catalyzed trans-hydrogenation, trans-hydrosilylation, trans-hydrogermylation, trans-hydrostannation, and even trans-hydroboration hold the promise of filling this gap. This review illustrates the state-of-the-art in the field by summarizing applications of these emerging methodologies to natural product synthesis. A comparison of ruthenium-catalyzed and radical-induced trans-hydrostannations provides further insights into the application profile of these transformations

Progress in the trans-Reduction and trans-Hydrometalation of Internal Alkynes. Applications to Natural Product Synthesis