Development of a Highly Sensitive and Selective Optical Chemical Sensor for the Determination of Zinc Based on Fluorescence Quenching of a Novel Schiff Base Ligand

A sensitive new optical sensor for Zn2+ is described. This optode is based on a\udnovel Schiff base ligand, 2-(2-hydroxy-5-chloro)benzaldehyde-[4-(3-methyl-3-mesitylcyclobutyl)-1,3-\udthiazol-2yl]hydrazone, in plasticized polyvinyl chloride membrane. This sensing membrane is capable\udof determining Zn2+ with a high sensitivity and selectivity over a wide dynamic range between\ud5.0×10−7 to 1.0×10−4 mol L−1 at pH 6.0 with a lower detection limit of 2.2×10−7 mol L−1 (14.4 g\udL−1 . The sensor can readily be regenerated with 1.0 mol L−1 EDTA solution. In addition to high stability,\udthe sensor shows a unique selectivity toward Zn2+ with respect to common metal cations. The\udsensor was successfully applied for the determination of zinc real samples. The results obtained\udfor the determination of zinc ions in hair samples using the proposed method was found to be\udcomparable with the well-established flame atomic absorption metho