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Analysis of the Nano-Surface of a Modified Glassy Carbon Electrode by Pseudo Phase Plane Method
Author(s) -
J. A. Tenreiro Machado,
Dumitru Băleanu,
Erdal Dіnç,
Alı Osman Solak,
Haslet Ekşi,
Remziye Güzel
Publication year - 2011
Publication title -
journal of computational and theoretical nanoscience
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.124
H-Index - 52
eISSN - 1546-1963
pISSN - 1546-1955
DOI - 10.1166/jctn.2011.1914
Subject(s) - materials science , glassy carbon , nano , surface (topology) , electrode , phase (matter) , plane (geometry) , carbon fibers , nanotechnology , analytical chemistry (journal) , composite material , electrochemistry , chemistry , mathematics , chromatography , cyclic voltammetry , geometry , organic chemistry , composite number
This paper presents the Pseudo phase plane (PPP) method for detecting the existence of a nanofilm on the nitroazobenzene-modified glassy carbon electrode (NAB-GC) system. This modified electrode systems and nitroazobenze-nanofilm were prepared by the electrochemical reduction of diazonium salt of NAB at the glassy carbon electrodes (GCE) in nonaqueous media. The IR spectra of the bare glassy carbon electrodes (GCE), the NAB-GC electrode system and the organic NAB film were recorded. The IR data of the bare GC, NAB-GC and NAB film were categorized into five series consisting of FILM1, GC-NAB1, GC1; FILM2, GC-NAB2, GC2; FILM3, GC-NAB3, GC3 and FILM4, GC-NAB4, GC4 respectively. The PPP approach was applied to each group of the data of unmodified and modified electrode systems with nanofilm. The results provided by PPP method show the existence of the NAB film on the modified GC electrode

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