Effects of Ultraviolet Light on Optical Properties of Colloidal CdS Nanoparticles Embedded in Polyvinyl Alcohol (PVA) Matrix
Author(s) -
G. Yu. Rudko,
Andrii Kovalchuk,
V. I. Fediv,
Jan Beyer,
Weimin Chen,
I. A. Buyanova
Publication year - 2012
Publication title -
advanced science engineering and medicine
Language(s) - English
Resource type - Journals
eISSN - 2164-6635
pISSN - 2164-6627
DOI - 10.1166/asem.2012.1174
Subject(s) - polyvinyl alcohol , photoluminescence , materials science , nanoparticle , nanocomposite , ultraviolet , chemical engineering , polymer , aqueous solution , ultraviolet light , colloid , ultraviolet visible spectroscopy , nanotechnology , chemistry , composite material , optoelectronics , organic chemistry , engineering
CdS nanoparticles have been synthesized in aqueous solution using polyvinyl alcohol (PVA) as a capping reagent. The effects of exposure by ultraviolet (UV) light on optical properties of nanocomposites consisting of colloidal CdS nanoparticles and a polymer PVA matrix were studied by employing photoluminescence (PL) spectroscopy. It is shown that UV-induced changes of the photoluminescence intensity in PVA are caused by creation and healing of non-radiative recombination centers. It is also concluded that in the nanocomposites, the UV-induced changes of the PL intensity are predominantly governed by processes at the NP/PVA interface.
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