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Laser Stimulation andObservation of Simple GasPhase Radical Reactions
Author(s) -
J. Wolfrum
Publication year - 1988
Publication title -
laser chemistry
Language(s) - English
Resource type - Journals
eISSN - 1026-8014
pISSN - 0278-6273
DOI - 10.1155/lc.9.171
Subject(s) - chemistry , stimulation , simple (philosophy) , gas phase , phase (matter) , laser , photochemistry , neuroscience , organic chemistry , optics , psychology , physics , epistemology , philosophy
Experiments on the effect of Selective vibrational, translational and orientations excitation of reactants in bimolecular reactions can give important insights into the microscopic dynamics of elementary chemical reactions. The information obtained in such experiments can be compared with the results of theoretical calculations of the reaction dynamics based on ab initio potential energy surfaces and is also of basic interest to improve the kinetic data used in detailed chemical kinetic modelling.

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