Laser Induced Synthesis: Condensation of Acrylonitrile on Carvone | Zendy

R. Stringat | Zendy; Flora Lemaire | Zendy; Roland Fellous | Zendy; AndréMichel Loiseau | Zendy

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Laser Induced Synthesis: Condensation of Acrylonitrile on Carvone

Author(s) -

R. Stringat,

Flora Lemaire,

Roland Fellous,

AndréMichel Loiseau

Publication year - 1988

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/lc.8.303

Subject(s) - acrylonitrile , chemistry , absorption (acoustics) , quantum yield , photochemistry , optics , fluorescence , organic chemistry , copolymer , physics , polymer

Laser irradiation of R(–) carvone in solution in acrylonitrile within the absorption bandof its n − π * transition (≃350 nm) leads to the formation of cyclobutanic adducts, together with traces of camphocarvone. The carvone transformation is complete and appears with high quantum efficiency.The quantum yield for intermolecular reaction is intensity dependent (13–30%). This is ascribed to the fact that the reaction takes place via both a one and a two-photon absorption channel, the second being even more efficient.

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