Infrared Multiphoton Dissociation of CF3CHClF: Primary Dissociation and Secondary Photolysis | Zendy

Shuji Kato | Zendy; Yoshihiro Makide | Zendy; Takeshi Tominaga | Zendy; Kazuo Takeuchi | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Infrared Multiphoton Dissociation of CF₃CHClF: Primary Dissociation and Secondary Photolysis

Author(s) -

Shuji Kato,

Yoshihiro Makide,

Takeshi Tominaga,

Kazuo Takeuchi

Publication year - 1987

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/lc.8.211

Subject(s) - dissociation (chemistry) , photodissociation , chemistry , infrared multiphoton dissociation , fluence , irradiation , photochemistry , infrared , laser , analytical chemistry (journal) , ion , organic chemistry , optics , physics , nuclear physics

The dissociation yield and branching ratio in CO 2 laser-induced infrared multiphoton dissociation (IRMPD) of CF 3 CHClF were investigated by irradiation at 9R(20) 1078.6 cm −1 under an unfocused irradiation geometry (0.75-2.3 J/cm 2 ) and a mildly focused one (1.2-18 J/cm 2 ). By using a Br 2 -scavenging technique, it was revealed that the primary dissociation of CF 3 CHClF proceeded mainly via three-centered HCl molecular elimination and C-Cl bond rupture, with minor contributions of C-C bond rupture and HF molecular elimination at higher fluences. The secondary photolysis of the primarily produced species during the laser pulse to yield CF 2 and CClF carbenes depended strongly upon the laser fluence.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research