Photodissociation of Cadmium Diiodide | Zendy

Kazuo Kasatani | Zendy; Koji Mori | Zendy; Masahiro Kawasaki | Zendy; Hiroyasu Sato | Zendy

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Photodissociation of Cadmium Diiodide

Author(s) -

Kazuo Kasatani,

Koji Mori,

Masahiro Kawasaki,

Hiroyasu Sato

Publication year - 1987

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/lc.7.95

Subject(s) - photodissociation , excited state , chemistry , cadmium , radical , absorption (acoustics) , laser , fluorescence , photochemistry , atomic physics , physics , optics , organic chemistry

Photodissociation of cadmium diiodide was studied. The nascent vibrational distributionof CdI(X 2 Σ ) on the photodissociation of CdI 2 at 308 nm was determined by thelaser-induced fluorescence (LIF) technique. The temporal variation in the density ofCdI(X 2 Σ ) radicals was monitored and it was shown that second-order recombination reactionswere important under our experimental conditions. Both the ground and thehighly excited states of cadmium atoms were generated on photodissociation of CdI 2 . Themultiphoton absorption process for the production of highly excited Cd atoms is discussed.

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