Frequency Dependent Kinetics of the CW CO2 Laser Induced Reaction of CF3CF2Cl | Zendy

R. N. Zitter | Zendy; David F. Koster | Zendy; N. Siddiqua | Zendy

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Frequency Dependent Kinetics of the CW CO2 Laser Induced Reaction of CF3CF2Cl

Author(s) -

R. N. Zitter,

David F. Koster,

N. Siddiqua

Publication year - 1986

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/lc.7.271

Subject(s) - chemistry , arrhenius equation , activation energy , kinetics , laser , reaction rate constant , torr , decomposition , analytical chemistry (journal) , absorption (acoustics) , range (aeronautics) , thermodynamics , optics , materials science , physics , organic chemistry , quantum mechanics , composite material

Kinetics of the decomposition of CF 3 CF 2 Cl at 50 torr by a cw CO 2 laser have been studied over a range of laser frequencies extending 36 cm −1 below an absorption bandcenter at 980 cm −1 . At constant translational temperature, the change in the rate constant with laser frequency is a factor of 100, comparable to the effect previously observed in CF 2 ClCF 2 Cl. Arrhenius plots show an activation energy of 86.2 kcal/mole, independent of frequency.

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