Picosecond 266-nm Multiphoton Laser Photolysis Studies on the Solvated Electron Formation Process in Water and Liquid Alcohols | Zendy

Hiroshi Miyasaka | Zendy; Hiroshi Masuhara | Zendy; Noboru Mataga | Zendy

Open Access

Picosecond 266-nm Multiphoton Laser Photolysis Studies on the Solvated Electron Formation Process in Water and Liquid Alcohols

Author(s) -

Hiroshi Miyasaka,

Hiroshi Masuhara,

Noboru Mataga

Publication year - 1987

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/lc.7.119

Subject(s) - solvated electron , picosecond , solvation , chemistry , radiolysis , photodissociation , ionization , photochemistry , electron , excitation , molecule , laser , atomic physics , ion , organic chemistry , radical , optics , physics , electrical engineering , engineering , quantum mechanics

A picosecond 266-nm multiphoton laser photolysis method was applied to the investigation of the solvation process of electrons in water and in several pure liquid alcohols. The formation time of the solvated electron obtained by this method in each liquid was revealed to be shorter than that obtained by picosecond pulse radiolysis and by the picosecond two-photon ionization of the solute molecules. By comparing the present results with those obtained by other methods, the effects of the excitation energy, as well as the solvation sphere of the relatively large parent cation on the solvated electron formation process, were elucidated.

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