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Chemiluminescence cross sections for reaction of the individual spin–orbit states ofmetastable Ca(P  J  03   ) with CH 3 I, CH 2 I 2 , and SF 6   have been determined by the use of optical pumping state selection. This technique was also used to separate the chemiluminescence arising from the two excited metastable Ca  3 P 0  and  1 D states. The spin–orbit dependence of the chemiluminescence pathway was found to be substantial for the CH 3 I and CH 2 I 2  reactions and similar to that previously observed for halogen diatom and alkyl bromide reagents. By contrast, no spin–orbit effect was observed for Ca( 3 P 0 )+SF 6 . These results are discussed in terms of our previously presented model for the origin of spin–orbit effects in chemical reactions.

laser chemistry

The Reaction of Spin–Orbit State-Selected C<scp>a</scp>(<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mmultiscripts><mml:mrow><mml:mo /><mml:mrow><mml:msubsup><mml:mi>P</mml:mi><mml:mi>J</mml:mi><mml:mn>0</mml:mn></mml:msubsup></mml:mrow><mml:mo /></mml:mrow><mml:mprescripts /><mml:none /><mml:mn>3</mml:mn></mml:mmultiscripts></mml:math>) With CH3I, CH2I2, and SF6

The Reaction of Spin–Orbit State-Selected Ca(PJ03) With CH3I, CH2I2, and SF6

The Reaction of Spin–Orbit State-Selected Ca(PJ03) With CH₃I, CH₂I₂, and SF₆