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The Hg—H 2  collision complex in the reaction Hg  3 P 1  + H 2  has been investigated by anew method involving the Van der Waals complex of the reactants. This method yieldsthe first observation of a vibrational transition in a reactive collision complex. Furthermorethe fixed geometry of the Van der Waals complex corresponding to the Hg  3 P 1 state enables the separation of two different reaction paths depending on the electronicconfiguration of the complex, namely    Σ    3    and    Π    3   .

Photochemistry in Van Der Waals Complexes: (Hg—H2)* → HgH + H

Photochemistry in Van Der Waals Complexes: (Hg—H₂)^* → HgH + H