Theoretical Methods for the Analysis of Spectra of Highly Vibrationally Excited Polyatomic Molecules | Zendy

F. Borondo | Zendy; J. M. Gomez Llorente | Zendy; R. M. Benito | Zendy

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Theoretical Methods for the Analysis of Spectra of Highly Vibrationally Excited Polyatomic Molecules

Author(s) -

F. Borondo,

J. M. Gomez Llorente,

R. M. Benito

Publication year - 1991

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/lc.12.85

Subject(s) - polyatomic ion , excited state , molecule , spectral line , chemistry , spectroscopy , atomic physics , chaotic , physics , quantum mechanics , computer science , organic chemistry , artificial intelligence

The vibrational spectra of classically chaotic systems are usually very complicated and seemingly unassignable. In this paper, two methods for the analysis of spectra of highly vibrationally excited polyatomic molecules are described, and some results for the floppy molecules HCN and LiNC are presented. By application of these methods, relevant information on the underlying dynamics is obtained, thus establishing a bridge between the spectroscopy and the dynamics of these systems.

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