Multiphoton Ionization of Nitrobenzene in Non-Aqueous Solutions: Characterization of the Cation and Ion-Molecule Chemistry | Zendy

Gary Siuzdak | Zendy; Joseph J. BelBruno | Zendy

Open Access

Multiphoton Ionization of Nitrobenzene in Non-Aqueous Solutions: Characterization of the Cation and Ion-Molecule Chemistry

Author(s) -

Gary Siuzdak,

Joseph J. BelBruno

Publication year - 1991

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/lc.11.83

Subject(s) - chemistry , nitrobenzene , aqueous solution , characterization (materials science) , ionization , ion , molecule , photochemistry , inorganic chemistry , computational chemistry , chemical physics , organic chemistry , nanotechnology , catalysis , materials science

The phenoxy cation has been generated in polar and nonpolar solutions by multiphoton ionization of nitrobenzene using nanosecond pulses of 266 nm and 355 nm light. The ions have been characterized by pulsed conductivity (ion mobility) measurements and transient absorption spectroscopy. The involvement of the phenoxy ion in ion-molecule chemistry with either neutral solute or solvent molecules has also been observed and the photochemical products and quantum yields of the ion-molecule products are presented and compared with the neutral photochemistry results.

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