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Laser Assisted Charge Exchange in Atomic Collisions
Author(s) -
J. F. Castillo,
L. F. Errea,
L. Méndez,
Antoni Riéra
Publication year - 1991
Publication title -
laser chemistry
Language(s) - English
Resource type - Journals
eISSN - 1026-8014
pISSN - 0278-6273
DOI - 10.1155/lc.11.285
Subject(s) - chemistry , atomic physics , laser , wavelength , radiative transfer , charge exchange , charge (physics) , field (mathematics) , cross section (physics) , physics , optics , ion , quantum mechanics , mathematics , organic chemistry , pure mathematics
We present total charge exchange cross sections for collisions of Li(1s22s2S) with H(1s) in presence of a linear polarized laser field of intensity 0.05 ≤ I ≤ 1 TW/cm2 and wavelength 5 103 ≤ λ ≤ 14 103 A. Our calculation shows that the laser field can increase the cross section of this reaction by a factor of ten at impact energies E < 0.1 ke V/a.m.u. The mechanism of this process is discussed and it is shown that both atomic and molecular radiative transitions can take place depending on the laser wavelength employed.

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