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CO2-laser induced multiple photon excitation and dissociation of the molecule (CF3)3CBr in the environment of I2 has been studied experimentally and theoretically. The synthesis of the (CF3)3CI molecule in laser-radical chemical reactions with high yield has been demonstrated.

laser chemistry

Multiple Photon IR Dissociation of (CF3)3CB<scp>r</scp> and Synthesis of (CF3)3CI in Laser-Radical Chemical Reactions

Multiple Photon IR Dissociation of (CF3)3CBr and Synthesis of (CF3)3CI in Laser-Radical Chemical Reactions

Multiple Photon IR Dissociation of (CF₃)₃CBr and Synthesis of (CF₃)₃CI in Laser-Radical Chemical Reactions