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[Retracted] Structural and Optical Properties of CdSe/CdTe Core‐Shell Quantum Dots
Author(s) -
G. Ramalingam,
C. Ragupathi,
R. Baskaran,
Ilhami Colak,
V. Vetrivelan,
Neda Poudineh,
Balasubramani Ravindran,
Soon Woong Chang,
Robert Moonsamy Gengan
Publication year - 2022
Publication title -
journal of nanomaterials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.463
H-Index - 66
eISSN - 1687-4129
pISSN - 1687-4110
DOI - 10.1155/2022/6316716
Subject(s) - materials science , quantum dot , cadmium telluride photovoltaics , core (optical fiber) , shell (structure) , optoelectronics , nanotechnology , composite material
A simple hydrothermal method is developed for the synthesis of high-quality type II core-shell CdSe/CdTe quantum dots (QDs). The XRD results reveal the formation of mixed phases of CdSe and CdTe with a grain size of 12.6 nm. SEM morphology confirms the uniformly distributed nanoscale CdSe/CdTe with no agglomeration. EDX confirms the elemental presence of Cd, Se, and Te in the compound. TEM results suggest that the size of spherical CdSe/CdTe core-shell QDs is in the range of 8~10 nm. Significant results of the SAED pattern confirm the core and shell components as CdSe and CdTe, respectively. The correlation between the synthesis procedures and the corresponding structures of the core-shell CdSe/CdTe QDs is discussed. The demonstrated monodispersed lattice structure of core-shell CdSe/CdTe QDs has excellent PL emission properties at λ emi ~ 585   nm which is suitable for photovoltaic applications. The UV-Vis absorption bands at 455 nm and 560 nm confirm exciton emission due to the type II matrix of CdSe/CdTe QDs.

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