Experimental Study on Reducing the Heat of Curing Reaction of Polyurethane Polymer Grouting Material

Polyurethane polymer grouting material has been effectively applied and promoted in the repair of road damages in nonfrozen areas. However, this material undergoes an exothermic reaction in the curing stage, which can cause a thermal disturbance in the frozen soil subgrade. To minimize the influence of the thermal disturbance of the polyurethane polymer grouting material in the repair of the frozen soil subgrade, an experiment was conducted to reduce the heat of the curing reaction under the influence of different proportions of a foaming agent, high-boiling point solvent, catalyst, and prepolymer. According to these test results, a proportioning scheme for the low exothermic polymer grouting material was formulated. The results indicated that the curing reaction temperature threshold of the polyurethane polymer grouting material was negatively related to the proportion of physical foaming agent (HCFC-141b) and high-boiling point solvent and positively related to the proportion of water weight. In the three stages of rapid temperature rise, slow temperature rise, and constant temperature, the rate of the temperature rise of the low exothermic polymer grouting material was lower than that of the common polymer, and the curing temperature threshold was 30.34% lower at a value of 101°C. At a density of 80 kg/m3, the compressive strength and tensile strength of the low heat release polymer grouting material were lower than those of the common polymer grouting material, thereby ensuring the excellent performance of polyurethane foam and providing a theoretical reference for the rapid repair of frozen soil roadbed diseases.