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Adsorptive Behavior of Prepared Metal-Organic Framework Composites on Phosphates in Aqueous Solutions
Author(s) -
Yan Zhao,
Hui-xuan Guo,
Hongguang Han,
Jiaqi Zhang,
Xiaomin Hu
Publication year - 2021
Publication title -
adsorption science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.682
H-Index - 36
eISSN - 2048-4038
pISSN - 0263-6174
DOI - 10.1155/2021/6690361
Subject(s) - adsorption , aqueous solution , chemistry , cyclic voltammetry , activated carbon , chemical engineering , desalination , phosphate , dielectric spectroscopy , electrochemistry , microstructure , wastewater , water treatment , inorganic chemistry , organic chemistry , membrane , electrode , waste management , biochemistry , engineering , crystallography
As an efficient water treatment method for treating dilute solution systems, electrosorption is promising for the separation and recovery of organic compounds, wastewater treatment, and deep purification of water. Here, two types of UiO-66 samples were prepared using the solvothermal synthesis method, and the effects of different regulators on the microstructure of materials were compared using the various characterization methods. The electrochemical properties of the activated carbon and two types of materials were tested by cyclic voltammetry and AC impedance spectroscopy, and the desalination effect of the materials on phosphate was investigated. The UiO-66 material with uniform-size particles, smaller-size particles, and more surface adsorption sites exhibited better phosphate removal and adsorption capacity. It was found that the desalination process of the UiO-66 material is reversible, and the adsorbent material can be reused, which is advantageous for engineering applications.

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