Synthesis, Crystal Structure, and Characterization of Ternary Copper(II) Complex Derived from N-(salicylidene)-L-valine | Zendy

Sundaramurthy Santha Lakshmi | Zendy; Kannappan Geetha | Zendy

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Synthesis, Crystal Structure, and Characterization of Ternary Copper(II) Complex Derived from N-(salicylidene)-L-valine

Author(s) -

Sundaramurthy Santha Lakshmi,

Kannappan Geetha

Publication year - 2016

Publication title -

journal of crystallography

Language(s) - English

Resource type - Journals

eISSN - 2356-7317

pISSN - 2314-5994

DOI - 10.1155/2016/6078543

Subject(s) - schiff base , copper , imine , crystallography , carboxylate , chemistry , denticity , ternary operation , crystal structure , diamine , chelation , stereochemistry , inorganic chemistry , polymer chemistry , organic chemistry , catalysis , computer science , programming language

Ternary Schiff base copper(II) complex [CuL(tmpda)] (where H2L is N-(salicylidene)-L-valine; tmpda is N,N,N′,N′-tetramethyl-1,3-propanediamine) has been characterized by UV-Vis., FTIR, and single crystal XRD. The crystal structure displays a distorted square pyramidal geometry in which Schiff base is bonded to the Cu(II) ion via phenolate oxygen, imine nitrogen, and an oxygen atom of the carboxylate group through the basal plane and the chelating diamine, N,N,N′,N′-tetramethyl-1,3-propanediamine, displays an axial and equatorial mode of binding via NN-donor atoms

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