Ammonia Sensing by PANI-DBSA Based Gas Sensor Exploiting Kelvin Probe Technique
Author(s) -
Anju Yadav,
Ajay Agarwal,
Pankaj Agarwal,
Parveen Saini
Publication year - 2015
Publication title -
journal of nanoparticles
Language(s) - English
Resource type - Journals
eISSN - 2314-4858
pISSN - 2314-484X
DOI - 10.1155/2015/842536
Subject(s) - polyaniline , materials science , conductive polymer , aniline , polymerization , kelvin probe force microscope , sulfonic acid , chemical engineering , monomer , doping , ammonia , polymer chemistry , polymer , nanotechnology , composite material , organic chemistry , optoelectronics , chemistry , atomic force microscopy , engineering
Dodecyl benzene sulfonic acid (DBSA) doped polyaniline (PANI-DBSA) has been synthesized by chemical oxidative polymerization of aniline monomer in the presence of DBSA. The UV-visible spectroscopy and X-ray diffraction measurements confirm the formation of PANI and its doping by DBSA. SEM images show the formation of submicron size rod shaped PANI particles. A vibrating capacitor based ammonia gas sensor was prepared by spin coating PANI-DBSA film over copper (Cu) substrate. The sensor exploited Kelvin probe technique to monitor contact potential difference between PANI and Cu as a function of time and ammonia concentration. Upon exposure to 30 ppm ammonia, the sensor displays response time of 329 s, recovery time of 3600 s, and sensitivity value of 1.54 along with good repeatability
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