Telomerization of Vinyl Chloride with Chloroform Initiated by Ferrous Chloride-Dimethylacetamide under Ultrasonic Conditions | Zendy

Hua Qian | Zendy; Hengdao Quan | Zendy

Open Access

Telomerization of Vinyl Chloride with Chloroform Initiated by Ferrous Chloride-Dimethylacetamide under Ultrasonic Conditions

Author(s) -

Hua Qian,

Hengdao Quan

Publication year - 2015

Publication title -

advances in chemistry

Language(s) - English

Resource type - Journals

eISSN - 2356-6612

pISSN - 2314-7571

DOI - 10.1155/2015/637653

Subject(s) - dimethylacetamide , chloroform , telomerization , chloride , ferrous , chemistry , vinyl chloride , yield (engineering) , polymer chemistry , organic chemistry , catalysis , nuclear chemistry , materials science , polymer , composite material , copolymer , solvent

Telomerization of vinyl chloride with chloroform was investigated using ferrous chloride-dimethylacetamide system, and 42.1% yield, more than four times the one reported before, was achieved. The addition of ultrasound further improved the reaction and yield was raised to 51.9% with trace byproducts at highly reduced reaction time and temperature. Ferrous chloride-dimethylacetamide under ultrasonic irradiation acts as a very efficient catalyst system for the 1 : 1 telomerization

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