Open AccessPerborate Oxidation of Substituted 5-Oxoacids in Aqueous Acetic Acid Medium: A Kinetic and Mechanistic Study
Author(s) -
S. Shree Devi,
B. Muthukumaran,
P. Krishnamoorthy
Publication year - 2014
Publication title -
isrn physical chemistry
Language(s) - English
Resource type - Journals
ISSN - 2090-7761
DOI - 10.1155/2014/924827
Subject(s) - chemistry , reaction rate constant , acetic acid , aqueous solution , reactivity (psychology) , reaction mechanism , kinetics , organic chemistry , catalysis , physics , quantum mechanics , medicine , alternative medicine , pathology
Kinetics and mechanism of oxidation of substituted 5-oxoacids by sodium perborate in aqueous acetic acid medium have been studied. The reaction exhibits first order both in [perborate] and [5-oxoacid] and second order in [H
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