Excitation Density Dependence of Optical Oxygen Sensing in Poly(9,9-dioctylfluorene) Waveguides Showing Amplified Spontaneous Emission
Author(s) -
M. Anni,
S. Lattante
Publication year - 2014
Publication title -
isrn materials science
Language(s) - English
Resource type - Journals
eISSN - 2090-6099
pISSN - 2090-6080
DOI - 10.1155/2014/856716
Subject(s) - amplified spontaneous emission , excitation , quenching (fluorescence) , spontaneous emission , materials science , fluorescence , oxygen , sensitivity (control systems) , limiting , optoelectronics , chemistry , optics , physics , laser , organic chemistry , quantum mechanics , mechanical engineering , electronic engineering , engineering
Reversible oxygen induced emission quenching of both the Spontaneous Emission (SE) and the Amplified Spontaneous Emission (ASE) of poly(9,9-dioctylfluorene) waveguides is demonstrated. We show that ASE shows a stronger quenching than SE, up to about 6.2 times, but also a stronger decrease when the excitation density increases. We conclude that the fast increase of the ASE decay rate is the main process in determining the ASE detection sensitivity, limiting the potentiality of sensitivity improvement of ASE with respect to SE.
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