The Effect of Cerium Oxide Addition on the Properties and Behavior of Y-TZP
Author(s) -
Dinesh Ragurajan,
Meenaloshini Satgunam,
Mohsen Golieskardi
Publication year - 2014
Publication title -
international scholarly research notices
Language(s) - English
Resource type - Journals
ISSN - 2356-7872
DOI - 10.1155/2014/828197
Subject(s) - materials science , sintering , fracture toughness , tetragonal crystal system , ceramic , vickers hardness test , modulus , composite material , phase (matter) , analytical chemistry (journal) , microstructure , chemistry , organic chemistry , chromatography
The effects of CeO 2 addition on the sintering behavior and mechanical properties of Y-TZP have been investigated over a wide sintering regime by pressureless sintering. It has been revealed that small additions of CeO 2 (0.3–1.0 wt%) to Y-TZP were beneficial in enhancing the mechanical properties and hydrothermal ageing resistance of Y-TZP. Sintered samples were used to evaluate the bulk density, Vickers's hardness, Young's modulus, and fracture toughness of the material. CeO 2 doped Y-TZPs were sintered at relatively low temperatures (1250°C and 1350°C) retaining high bulk density (>97% of theoretical density) and high Young's modulus (>200 GPa) without sacrificing tetragonal phase stability. The optimum level of dopant was found to be at 0.5 wt% for sintering between 1250°C and 1450°C using the standard 2 h holding time cycle, with sintered body exhibiting excellent combination of properties when compared to the undoped ceramics. In this experiment, the addition of 0.5 wt% recorded a bulk density reading of 5.9 g/cm 3 , Vickers hardness value of 13.2 GPa, Young's modulus value of 211 GPa, and fracture toughness of 6.4 MPam 1/2 , respectively, in a temperature range of 1400–1450°C.
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