Kinetics and Mechanism of Micellar Catalyzed Oxidation of Dextrose by N-Bromosuccinimide in H2SO4 Medium | Zendy

Minu Singh | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Kinetics and Mechanism of Micellar Catalyzed Oxidation of Dextrose by N-Bromosuccinimide in H₂SO₄ Medium

Author(s) -

Minu Singh

Publication year - 2014

Publication title -

international journal of carbohydrate chemistry

Language(s) - English

Resource type - Journals

eISSN - 1687-935X

pISSN - 1687-9341

DOI - 10.1155/2014/783521

Subject(s) - chemistry , stoichiometry , n bromosuccinimide , arrhenius equation , catalysis , order of reaction , activation energy , kinetics , reaction mechanism , acrylonitrile , reaction rate , rate equation , sulfuric acid , chemical kinetics , inorganic chemistry , reaction rate constant , organic chemistry , halogenation , copolymer , polymer , physics , quantum mechanics

Kinetics and mechanism of micellar catalyzed N-bromosuccinimide oxidation of dextrose in H2SO4 medium was investigated under pseudo-first-order condition temperature of 40°C. The results of the reactions studied over a wide range of experimental conditions show that NBS shows a first order dependence, fractional order, on dextrose and negative fractional order dependence on sulfuric acid. The determined stoichiometric ratio was 1 : 1 (dextrose : N-bromosuccinimide). The variation of Hg(OAC)2 and succinimide (reaction product) has insignificant effect on reaction rate. Effects of surfactants, added acrylonitrile, added salts, and solvent composition variation have been studied. The Arrhenius activation energy and other thermodynamic activation parameters are evaluated. The rate law has been derived on the basis of obtained data. A plausible mechanism has been proposed from the results of kinetic studies, reaction stoichiometry, and product analysis. The role of anionic and nonionic micelle was best explained by the Berezin’s model

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research