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The Galerkin Finite Element Method (GFEM) with 8- and 27-node hexahedrons elements is used for solving diffusion and transient three-dimensional reaction-diffusion with singularities. Besides analyzing the results from the primary variable (temperature), the finite element approximations were used to find the derivative of the temperature in all three directions. This technique does not provide an order of accuracy compatible with the one found in the temperature solution; thereto, a calculation from the third order finite differences  is proposed here, which provide the best results, as demonstrated by the first two applications proposed in this paper. Lastly, the presentation and the discussion of a real application with two cases of boundary conditions with singularities are proposed

3D Unsteady Diffusion and Reaction-Diffusion with Singularities by GFEM with 27-Node Hexahedrons