Adsorbent Ability of Treated Peganum harmala-L Seeds for the Removal of Ni (II) from Aqueous Solutions: Kinetic, Equilibrium and Thermodynamic Studies
Author(s) -
Maryam Ghasemi,
Nahid Ghasemi,
Javad Azimi-Amin
Publication year - 2014
Publication title -
indian journal of materials science
Language(s) - English
Resource type - Journals
ISSN - 2314-7490
DOI - 10.1155/2014/459674
Subject(s) - adsorption , aqueous solution , peganum harmala , langmuir , kinetics , chemistry , langmuir adsorption model , thermodynamics , chromatography , materials science , physics , botany , biology , quantum mechanics
The main goal of this study was to evaluate the performance of new adsorbent, treated Peganum harmala-L seeds (TPHS), for the removal of Ni (II) from aqueous solution. Batch experiments were performed as a function of various experimental parameters. The adsorption studies included both equilibrium adsorption isotherms and kinetics. Equilibrium data fitted very well with the Langmuir isotherm model. Maximum adsorption capacity was determined 91.74 mg/g at pH 7. Kinetics studies showed better applicability for pseudo-second-order model for both adsorbents. The negative value of ΔG° confirmed the feasibility and spontaneity of TPHS for Ni (II) adsorption
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