Synthesis of V2O5 Nanoflakes on PET Fiber as Visible-Light-Driven Photocatalysts for Degradation of RhB Dye
Author(s) -
Yim-Leng Chan,
SweeYong Pung,
Srimala Sreekantan
Publication year - 2014
Publication title -
journal of catalysts
Language(s) - English
Resource type - Journals
eISSN - 2314-5102
pISSN - 2314-5110
DOI - 10.1155/2014/370696
Subject(s) - photodegradation , rhodamine b , photocatalysis , materials science , visible spectrum , substrate (aquarium) , semiconductor , chemical engineering , nanotechnology , photochemistry , optoelectronics , catalysis , chemistry , organic chemistry , oceanography , engineering , geology
The visible-light-driven semiconductor photocatalysts are the current research focus techniques used to decompose organic pollutants/compounds. The photodegradation efficiency of organic compounds by photocatalyst is expected to be better compared to UV-light-driven semiconductor photocatalysts technique since the major components of our solar energy are visible light (~44%). However, as most of the previous research work has been carried out using semiconductor photocatalysts in the form of powder, extra steps and costs are needed to remove this powder from the slurry to prevent secondary pollution. In this research work, we will explain our fabrication technique of V2O5 nanoflakes by growing radially on PET fibers. By utilizing the flexibility and high surface area of polymeric fibers as novel substrate for the growth of V2O5 nanoflakes, the Rhodamine B (RhB) could be degraded under visible light irradiation. The photodegradation of RhB solution by V2O5 nanoflakes followed the 1st order kinetic with a constant rate of 0.0065 min−1. The success of this research work indicates that V2O5 nanoflakes grown on PET fibre could be possibly used as organic waste water purifier under continuous flow condition. A photodegradation mechanism of V2O5 nanostructures to degrade RhB dye is proposed based on the energy diagram
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