“Mohsite” of Colomba: Identification as Dessauite-(Y)
Author(s) -
Erica Bittarello,
Marco E. Ciriotti,
Emanuele Costa,
Lorenzo Gallo
Publication year - 2014
Publication title -
international journal of mineralogy
Language(s) - English
Resource type - Journals
eISSN - 2356-7058
pISSN - 2314-6036
DOI - 10.1155/2014/287069
Subject(s) - materials science
During a reorganization of the mineralogical collection of Turin University, old samples of the so-called mohsite of Colomba were found. “Mohsite” was discredited in 1979 by Kelly et al., as a result of some analyses performed on the equivalent material coming from the French region of Hautes-Alpes, but the original samples found in similar geological setting in Italy were lost and never analysed with modern equipment. After more than a century, the rediscovered samples of Professor Colomba were analysed by means of SEM-EDS analysis, microRaman spectroscopy, and X-ray diffraction. The results have demonstrated that the historical samples studied by Colomba are Pb-free dessauite-(Y), and pointed to an idealized crystal chemical formula (Sr0.70Na0.25Ca0.09)Σ=1.04 (Y0.62U0.18Yb0.09Sc0.08)Σ=0.97 (Ti12.66)Σ=17.70O38 and unit-cell parameters a = 10.376(3) A, c = 20.903(6) A, and V = 1949(1) A3.
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