Synthesis and Crystal Structure of Alkynylplatinum(IV) Complex Containing the Terpyridine Ligand | Zendy

Tsugiko Takase | Zendy; Dai Oyama | Zendy

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Synthesis and Crystal Structure of Alkynylplatinum(IV) Complex Containing the Terpyridine Ligand

Author(s) -

Tsugiko Takase,

Dai Oyama

Publication year - 2014

Publication title -

journal of crystallography

Language(s) - English

Resource type - Journals

eISSN - 2356-7317

pISSN - 2314-5994

DOI - 10.1155/2014/280247

Subject(s) - terpyridine , ligand (biochemistry) , octahedron , chemistry , crystallography , algorithm , crystal structure , computer science , biochemistry , receptor , organic chemistry , metal

Reaction of square planar [PtII(C≡CPh)(tpy)]+ (tpy = 2,2′:6′,2′′-terpyridine) with bromine at low temperature provides a general route for the synthesis of octahedral alkynyl(terpyridine)platinum(IV) complex. In this first example of alkynyl(terpyridine)platinum(IV) complex, the alkynyl group is situated in trans position relative to the central nitrogen atom of the terpyridine ligand, and the two bromido ligands are situated in trans positions; an X-ray structural analysis has been completed for trans(Br)-[PtIVBr2(C≡CPh)(tpy)]+

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