Molecular Structure and Crystal Packing of n-Type Semiconducting Material 3′,3′-(1,4-Phenylene)bis{2′-(4′′-trifluoromethyl)phenyl}acrylonitrile | Zendy

Tetsuji Moriguchi | Zendy; Shuichi Nagamatsu | Zendy; Tatsuo Okauchi | Zendy; Akihiko Tsuge | Zendy; Wataru Takashima | Zendy; Shuji Hayase | Zendy

Open Access

Molecular Structure and Crystal Packing of n-Type Semiconducting Material 3′,3′-(1,4-Phenylene)bis{2′-(4′′-trifluoromethyl)phenyl}acrylonitrile

Author(s) -

Tetsuji Moriguchi,

Shuichi Nagamatsu,

Tatsuo Okauchi,

Akihiko Tsuge,

Wataru Takashima,

Shuji Hayase

Publication year - 2014

Publication title -

journal of crystallography

Language(s) - English

Resource type - Journals

eISSN - 2356-7317

pISSN - 2314-5994

DOI - 10.1155/2014/257249

Subject(s) - acrylonitrile , trifluoromethyl , crystallography , stacking , materials science , intermolecular force , dichloromethane , phenylene , crystal structure , single crystal , crystal (programming language) , chemistry , molecule , solvent , polymer , organic chemistry , alkyl , copolymer , composite material , computer science , programming language

The exact molecular structure and the crystal packing of the n-type semiconducting material 3′,3′-(1,4-phenylene)bis{2′-(4′′-trifluoromethyl)phenyl}acrylonitrile was determined by a single crystal X-ray diffraction with twin treatment technique. The air-stable product was crystallized from dichloromethane-hexane mixed solution. The solid-state structure is the example of a typical π-π stacking with side intermolecular CN–H short contact networks

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