Study of Complexation in Acetone-Chloroform Mixtures by Infrared Spectroscopy | Zendy

Oleksii Ilchenko | Zendy; Andrii Kutsyk | Zendy; Vyacheslav V. Obukhovsky | Zendy

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Study of Complexation in Acetone-Chloroform Mixtures by Infrared Spectroscopy

Author(s) -

Oleksii Ilchenko,

Andrii Kutsyk,

Vyacheslav V. Obukhovsky

Publication year - 2014

Publication title -

journal of atomic and molecular physics

Language(s) - English

Resource type - Journals

ISSN - 2314-8039

DOI - 10.1155/2014/106178

Subject(s) - chloroform , acetone , fourier transform infrared spectroscopy , chemistry , infrared spectroscopy , analytical chemistry (journal) , decomposition , infrared , spectroscopy , resolution (logic) , chromatography , organic chemistry , optics , physics , quantum mechanics , artificial intelligence , computer science

FTIR spectra of acetone-chloroform system with various component ratios were investigated within the spectral range 3950–4550 cm−1. Methods of multivariate curve resolution were applied to decompose the FTIR spectra into specific components of different composition. A method of decomposition based on structural model of solution which contains acetone, chloroform, and complex acetone/chloroform (1 : 1) was proposed. Results of both approaches are in good agreement within the range of measuring error.

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