Study of the Behavior of Titanium Alloys as the Cathode for Photovoltaic Hydrogen Production | Zendy

Chien-Lung Huang | Zendy; Yujia Gao | Zendy; Tao-Liang Chuang | Zendy; Vincent K. S. Hsiao | Zendy; Tair-I Wu | Zendy

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Study of the Behavior of Titanium Alloys as the Cathode for Photovoltaic Hydrogen Production

Author(s) -

Chien-Lung Huang,

Yujia Gao,

Tao-Liang Chuang,

Vincent K. S. Hsiao,

Tair-I Wu

Publication year - 2013

Publication title -

international journal of photoenergy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.426

H-Index - 51

eISSN - 1687-529X

pISSN - 1110-662X

DOI - 10.1155/2013/857491

Subject(s) - thiourea , tungsten trioxide , hydrogen production , hydrogen , materials science , electrochemistry , cathode , titanium , trioxide , photovoltaic system , chemical engineering , anode , inorganic chemistry , metallurgy , chemistry , electrode , sulfur , tungsten , organic chemistry , ecology , biology , engineering

CP-Ti and Ti-153 were adopted in this study to observe their electrochemical behavior in serving as the cathode for photovoltaic hydrogen production. The designed cyclic hydrogenation-solution heat treating processes were performed to increase the hydrogen uptake for both alloys. The results are as follows. (1) Both arsenic trioxide and thiourea showed hydrogenation promotive effect on CP-Ti, while thiourea was an inhibitor for Ti-153 under the applied conditions. (2) Arsenic trioxide showed hydrogenation promotive effect on both Ti-153 and CP-Ti in this study. (3) Ti-153 demonstrated superiority to CP-Ti when serves as the cathode for photovoltaic hydrogen production. The hydrogen mass payload for Ti-153 is 68 times larger than that for CP-Ti

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