Application of Electron Beam Melting to the Removal of Phosphorus from Silicon: Toward Production of Solar-Grade Silicon by Metallurgical Processes
Author(s) -
Hideaki Sasaki,
Yoshifumi Kobashi,
Takashi Nagai,
Masafumi Maeda
Publication year - 2013
Publication title -
advances in materials science and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.356
H-Index - 42
eISSN - 1687-8442
pISSN - 1687-8434
DOI - 10.1155/2013/857196
Subject(s) - silicon , materials science , impurity , refining (metallurgy) , phosphorus , cathode ray , metallurgy , evaporation , melting temperature , electron , composite material , thermodynamics , chemistry , physics , organic chemistry , quantum mechanics
Removal methods of impurity from metallurgical-grade silicon (Si) are intensively studied to produce solar-grade silicon (SoG-Si) with a smaller economical load and lower cost. Removal of phosphorus (P) has been an important issue because of difficulties in application of conventional metallurgical methods such as solidification refining. Because P evaporates preferentially from molten Si due to its high vapor pressure, electron beam (EB) melting has been applied to the purification of Si. The evaporation of impurity P from Si is considered based on previous thermodynamic investigations here, and several research reports on EB melting of Si are reviewed
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