A New 3D Coordination Polymer of Bismuth with Nicotinic Acid N‐Oxide | Zendy

Farzin Marandi | Zendy; Ingo Pantenburg | Zendy; Gerd Meyer | Zendy

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A New 3D Coordination Polymer of Bismuth with Nicotinic Acid N‐Oxide

Author(s) -

Farzin Marandi,

Ingo Pantenburg,

Gerd Meyer

Publication year - 2013

Publication title -

journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.436

H-Index - 50

eISSN - 2090-9063

pISSN - 2090-9071

DOI - 10.1155/2013/845810

Subject(s) - chemistry , monoclinic crystal system , thermogravimetric analysis , coordination polymer , bismuth , crystallography , oxide , molecule , single crystal , elemental analysis , polymer , crystal structure , thermal stability , powder diffraction , infrared spectroscopy , inorganic chemistry , organic chemistry

The new three-dimensional coordination polymer {[Bi(NNO)2(NO3)]·1.5H2O}n (1, NNO− = nicotinate N-oxide) was synthesized and characterized by elemental analysis, IR and 1H-NMR spectroscopy, as well as single-crystal X-ray diffraction analysis. 1 crystallizes in the monoclinic space group C2/c. The crystal structure consists of a rectangular-shaped grid constructed with NNO linkers. Cavities of a diameter of 7.9–8.3 Å2 are filled with disordered water molecules. The thermal stability of the compound was evaluated by thermogravimetric analysis

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