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Synthesis and Characterization of Metallic Gel Complexes Derived from Carboxymethyl Cellulose
Author(s) -
Harjeet D. Juneja,
Manisha Joshi,
J. P. Kanfade
Publication year - 2012
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.436
H-Index - 50
eISSN - 2090-9063
pISSN - 2090-9071
DOI - 10.1155/2013/820328
Subject(s) - chemistry , carboxymethyl cellulose , characterization (materials science) , metal , cellulose , polymer chemistry , organic chemistry , nanotechnology , sodium , materials science
The oxaloyl carboxymethyl cellulose (OCMC) complexes of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) metal ions have been synthesized and the coordination of OCMC in these complexes has been investigated through IR spectra, reflectance spectra, and thermal analysis. On the basis of spectral and thermal data an octahedral geometry was assigned to [Mn(II)OCMC(H2O)2]n and [Co(II)OCMC(H2O)2]n, square planar geometry was assigned to [Cu(II)OCMC]n, and tetrahedral geometry was assigned to [Ni(II)OCMC]n and [Zn(II)OCMC]n Metallic Gel complexes

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