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Synthesis of Nitrogen-Doped ZnS with Camellia Brushfield Yellow Nanostructures for Enhanced Photocatalytic Activity under Visible Light Irradiation
Author(s) -
Gang-Juan Lee,
Chi-Lun Hong,
V. N. Batalova,
Г. М. Мокроусов,
Jerry J. Wu
Publication year - 2013
Publication title -
international journal of photoenergy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.426
H-Index - 51
eISSN - 1687-529X
pISSN - 1110-662X
DOI - 10.1155/2013/801846
Subject(s) - photocatalysis , x ray photoelectron spectroscopy , materials science , visible spectrum , scanning electron microscope , zinc sulfide , nitrogen , doping , transmission electron microscopy , raman spectroscopy , nuclear chemistry , methyl orange , photochemistry , analytical chemistry (journal) , catalysis , nanotechnology , chemistry , zinc , chemical engineering , optics , optoelectronics , biochemistry , physics , organic chemistry , chromatography , engineering , metallurgy , composite material
Nitrogen modified zinc sulfide photocatalysts were successfully prepared and characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), X-ray photoelectron spectroscopy (XPS), and surface area analysis. Thermal decomposition of the semisolid was carried out under nitrogen conditions at 500°C for 2 hours, and a series of nitrogen-doped ZnS photocatalysts were produced by controlling inflow flow rate of nitrogen at 15–140 mL/min. Optical characterizations of the synthesized N-doping ZnS substantially show the shifted photoabsorption properties from ultraviolet (UV) region to visible light. The band gaps of nitrogen-doped ZnS composite catalysts were calculated to be in the range of 2.58~2.74 eV from the absorptions edge position. The 15N/ZnS catalyst shows the highest photocatalytic activity, which results in 75.7% degradation of Orange II dye in 5 hrs by visible light irradiation, compared with pristine ZnS and higher percentage N-doping ZnS photocatalysts

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